Black residue on leaves beneath a tree can look like someone dusted the garden with fireplace ash. The culprit often has a much more interesting story: sap-sucking insects feed high in the canopy, leave behind sticky honeydew, and sooty mold grows on that sugary mess as it falls onto lower leaves. Aphids and soft scale insects commonly create this chain reaction, and the black coating can show up on leaves, twigs, patio furniture, cars, and anything else sitting beneath the tree.
The good news is that the black material usually does not mean the tree itself has caught some mysterious black-leaf disease. Sooty mold does not attack plant tissue the way many disease-causing fungi do, although a heavy coating can interfere with photosynthesis and signal that a substantial insect population sits somewhere above. The trick involves finding the insects instead of simply scrubbing away the evidence.