
If any two people suit the term multi-hyphenate, it's Brangelina.
Even before the pair were together, they shared a vision greater than the realms of acting. Jolie served as Goodwill Ambassador for the United Nations for 11 years from 2001 and Pitt co-authored an architecture book back in 2000. This philanthropy and side-hustling continued throughout their relationship, and now the pair are running their own brands: Brad with his skincare line, Le Domaine, and winery, Miraval, and Jolie with her new fashion line, Atelier Jolie. During their marriage, they also amassed a substantial property portfolio, which has become a sticking point during their ongoing, seven-year-long divorce.